6-Methylpyridin-2-amine
نویسندگان
چکیده
In the title mol-ecule, C6H8N2, the endocyclic angles are in the range 118.43 (9)-122.65 (10)°. The mol-ecular skeleton is planar (r.m.s. deviation = 0.007 Å). One of the two amino H atoms is involved in an N-H⋯N hydrogen bond, forming an inversion dimer, while the other amino H atom participates in N-H⋯π inter-actions between the dimers, forming layers parallel to (100).
منابع مشابه
6-Methylpyridin-3-amine
In the mol-ecule of the title compound, C(6)H(8)N(2), the methyl C and amine N atoms are 0.021 (2) and 0.058 (2) Å from the pyridine ring plane. In the crystal structure, inter-molecular N-H⋯N hydrogen bonds link the mol-ecules.
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In the title compound, C(6)H(6)Cl(2)N(2), intra-molecular N-H⋯Cl and C-H⋯Cl contacts generate five-membered rings, producing S(5) ring motifs. Pairs of inter-molecular N-H⋯N hydrogen bonds link neighbouring mol-ecules into dimers with R(2) (2)(8) ring motifs. In the crystal structure, these dimers are connected by N-H⋯Cl inter-actions and are packed into columns.
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The mononuclear copper title complex {N,N,N',N'-tetra-kis-[(6-methyl-pyridin-2-yl)meth-yl]ethane-1,2-di-amine-κ6N}copper(II) bis-(tetra-fluorido-borate), [Cu(C30H36N6)](BF4)2, is conveniently prepared from the reaction of Cu(BF4)2·6H2O with N,N,N',N'-tetra-kis-[(6-methyl-pyridin-2-yl)meth-yl]ethane-1,2-di-amine (tmpen) in aceto-nitrile at room temperature in air. The complex shows a distorted o...
متن کاملCrystal structure and electrochemical properties of [Ni(bztmpen)(CH3CN)](BF4)2 {bztmpen is N-benzyl-N,N′,N′-tris[(6-methylpyridin-2-yl)methyl]ethane-1,2-diamine}
The mononuclear nickel title complex (acetonitrile-κN){N-benzyl-N,N',N'-tris-[(6-methyl-pyridin-2-yl)meth-yl]ethane-1,2-di-amine}-nickel(II) bis-(tetra-fluor-ido-borate), [Ni(C30H35N5)(CH3CN)](BF4)2, was prepared from the reaction of Ni(BF4)2·6H2O with N-benzyl-N,N',N'-tris-[(6-methyl-pyridin-2-yl)meth-yl]ethane-1,2-di-amine (bztmpen) in aceto-nitrile at room temperature. With an open site occu...
متن کاملN-(4-Chlorophenyl)-4-methylpyridin-2-amine
In the title compound, C(12)H(11)ClN(2), the dihedral angle between the benzene and pyridyl rings is 48.03 (8)°. Twists are also evident in the mol-ecule, in particular about the N(a)-C(b) (a = amine and b = benzene) bond [C-N-C-C = -144.79 (18)°]. In the crystal, inversion dimers linked by pairs of N-H⋯N hydrogen bonds result in the formation of eight-membered {⋯NCNH}(2) synthons [or R(2) (2)(...
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